This MCQ module is based on: Salts and Their Uses
Salts and Their Uses
2.4 More About Salts
In the previous sections, we saw that salts are formed when acids react with bases. But there is much more to know about salts — they form families, have different pH values, and many of them have crucial industrial and domestic uses.
2.4.1 Family of Salts
- Write the chemical formulae of sodium sulphate (Na2SO4), potassium sulphate (K2SO4), and calcium sulphate (CaSO4).
- Now write the formulae of sodium chloride (NaCl), potassium chloride (KCl), and calcium chloride (CaCl2).
- Identify the common part in each group.
| Sulphate family (from H2SO4) | Chloride family (from HCl) |
|---|---|
| Na2SO4 | NaCl |
| K2SO4 | KCl |
| CaSO4 | CaCl2 |
Salts that share the same acid origin (same anion) belong to the same family. The sulphate family comes from H2SO4, the chloride family from HCl, the nitrate family from HNO3, and so on.
2.4.2 pH of Salts
Not all salts are neutral. The pH of a salt depends on the strengths of the acid and base that formed it:
| Acid Strength | Base Strength | Salt pH | Example |
|---|---|---|---|
| Strong (HCl) | Strong (NaOH) | pH = 7 (Neutral) | NaCl |
| Strong (HCl) | Weak (NH4OH) | pH < 7 (Acidic) | NH4Cl |
| Weak (CH3COOH) | Strong (NaOH) | pH > 7 (Basic) | CH3COONa |
Some common natural sources of acids:
| Natural Source | Acid Present |
|---|---|
| Vinegar | Acetic acid (CH3COOH) |
| Orange / Lemon | Citric acid |
| Tamarind (imli) | Tartaric acid |
| Tomato | Oxalic acid |
| Curd / Sour milk | Lactic acid |
| Ant / Bee sting | Methanoic acid (formic acid) |
2.4.3 Common Salt (NaCl) — The Starting Material
Common salt (NaCl) is obtained by evaporation of sea water or mined from underground rock salt deposits. It is one of the most important raw materials in the chemical industry, providing the starting point for manufacturing several key chemicals.
2.4.4 Sodium Hydroxide (NaOH) — The Chlor-Alkali Process
When electricity is passed through a concentrated solution of sodium chloride (brine), it decomposes to give three useful products:
This process is called the chlor-alkali process because of the two main products — chlor(ine) and (alk)ali (NaOH).
Uses of the three products:
| Product | Uses |
|---|---|
| NaOH | Soap and detergent making, paper manufacturing, de-greasing metals, petroleum refining |
| Cl2 | Water purification, PVC plastics, disinfectants, CFC compounds, bleaching powder |
| H2 | Fuels, margarine production, ammonia synthesis (for fertilisers) |
2.4.5 Bleaching Powder (CaOCl2)
Bleaching powder is produced when chlorine gas reacts with dry slaked lime:
Uses: (i) Bleaching cotton, linen, and wood pulp in the textile and paper industry. (ii) Disinfecting drinking water to make it germ-free. (iii) Oxidising agent in many chemical industries.
2.4.6 Baking Soda (NaHCO3)
Baking soda (sodium hydrogen carbonate, NaHCO3) is produced using common salt as the starting material:
When heated, baking soda decomposes:
2.4.7 Washing Soda (Na2CO3·10H2O)
Washing soda is obtained by recrystallising sodium carbonate with 10 molecules of water:
The Na2CO3 itself is obtained by heating baking soda:
Uses of washing soda: (i) Cleaning agent — removes grease and dirt. (ii) Softening hard water by removing Ca2+ and Mg2+ ions. (iii) Manufacturing of glass, soap, and paper. (iv) Manufacture of sodium compounds like borax.
2.4.8 Plaster of Paris (CaSO4·½H2O)
Plaster of Paris is obtained by heating gypsum (CaSO4·2H2O) at 373 K (100°C):
When Plaster of Paris is mixed with water, it sets into a hard mass by reverting back to gypsum:
Uses: (i) Setting fractured bones as plaster casts. (ii) Making decorative items, toys, and statues. (iii) Making smooth surfaces (wall finishing). (iv) Making moulds in pottery and dentistry. (v) Making chalk for writing on blackboards.
Water of Crystallisation
Water of crystallisation is the fixed number of water molecules present in one formula unit of a salt in its crystalline form. For example, CuSO4·5H2O has 5 water molecules, Na2CO3·10H2O has 10, and CaSO4·2H2O has 2.
- Take a few crystals of copper sulphate (CuSO4·5H2O) in a dry boiling tube. Note the blue colour.
- Heat the crystals gently over a flame. Observe the colour change and any moisture on the tube walls.
- After the crystals become completely white, let the tube cool.
- Add 2-3 drops of water to the white powder and observe.
On heating, the blue CuSO4·5H2O crystals gradually turn white. Water droplets appear on the cooler parts of the boiling tube. When water is added back to the white powder, it turns blue again.
(blue) → (white) + (water vapour)
This experiment confirms that the blue colour of copper sulphate crystals is due to the water of crystallisation. When these water molecules are removed, the substance loses its blue colour and turns white.
Competency-Based Questions
Q1. L1 Remember What is the chemical formula of Plaster of Paris?
Q2. L2 Understand Explain why baking soda is used as an ingredient in antacid tablets. (2 marks)
Q3. L3 Apply Write the balanced equation for the preparation of bleaching powder. Name the raw materials needed. (2 marks)
\(\text{Ca(OH)}_2 + \text{Cl}_2 \rightarrow \text{CaOCl}_2 + \text{H}_2\text{O}\)
Raw materials needed: Dry slaked lime — Ca(OH)2, and chlorine gas — Cl2 (obtained from the chlor-alkali process).
Q4. L4 Analyse In the chlor-alkali process, why are the products (NaOH, Cl2, H2) formed at different electrodes? What would happen if Cl2 and NaOH came into contact? (3 marks)
Q5. L5 Evaluate A student says, "Since washing soda and baking soda are both sodium compounds, they can be used interchangeably." Evaluate this claim. (3 marks)
Assertion-Reason Questions
Assertion (A): Plaster of Paris should be stored in moisture-proof containers.
Reason (R): Plaster of Paris absorbs water (moisture) and slowly sets into hard gypsum, making it useless.
Assertion (A): The blue colour of copper sulphate crystals disappears on strong heating.
Reason (R): Copper sulphate pentahydrate loses its water of crystallisation on heating, leaving behind white anhydrous copper sulphate.
Assertion (A): A salt formed from a strong acid and a weak base will have a pH less than 7.
Reason (R): Such salts are acidic in nature because the strong acid dominates.