This MCQ module is based on: Acids and Bases in Water and the pH Scale
Acids and Bases in Water and the pH Scale
2.2 What Do All Acids and All Bases Have in Common?
We have seen that acids react with metals, bases, and carbonates. But what is the fundamental chemical reason behind the acidic behaviour? The answer lies in what happens when acids dissolve in water.
Acids Produce H+ Ions in Water
When an acid dissolves in water, it releases hydrogen ions — H+(aq). These H+ ions are responsible for all the typical properties of acids.
The H+ ion is actually a bare proton. In water, it immediately bonds to a water molecule forming the hydronium ion:
Bases Produce OH- Ions in Water
Bases that dissolve in water release hydroxide ions — OH-(aq):
- Prepare separate solutions of glucose, alcohol, hydrochloric acid, and sodium hydroxide in water.
- Set up a circuit with a battery, bulb, and two electrodes dipping into each solution in turn.
- Observe which solutions make the bulb glow.
The bulb glows for HCl and NaOH solutions, but does not glow for glucose and alcohol solutions.
Explanation: HCl and NaOH produce ions (H+/Cl- and Na+/OH-) in water. These ions carry electric current. Glucose and alcohol dissolve but do not produce ions — they exist as neutral molecules in solution. Since no ions are present, no current flows.
- Place dry blue litmus paper in a gas jar filled with dry HCl gas.
- Observe any colour change.
- Now moisten another piece of blue litmus paper with water and place it in the same dry HCl gas.
- Compare the results.
Dry litmus paper shows no colour change in dry HCl gas. But moist litmus paper immediately turns red.
Explanation: Dry HCl gas does not contain H+ ions — it is just HCl molecules. Only when HCl dissolves in water does it ionise to produce H+ ions. It is these H+(aq) ions that turn litmus red. Water is essential for acids to show their acidic character.
2.3 How Strong Are Acid or Base Solutions?
Not all acids are equally strong. Hydrochloric acid (HCl) is much stronger than acetic acid (vinegar). Scientists measure the strength of an acidic or basic solution using the pH scale.
The pH Scale (0 to 14)
| pH Range | Nature | H+ Ion Concentration |
|---|---|---|
| pH < 7 | Acidic | High (more H+ ions) |
| pH = 7 | Neutral | Equal H+ and OH- |
| pH > 7 | Basic (alkaline) | Low (fewer H+ ions, more OH-) |
The lower the pH, the stronger the acid. The higher the pH (above 7), the stronger the base.
Interactive: Explore the pH Scale L3 Apply
Drag the slider to explore different pH values and see common substances at each level.
Example: Pure water. Neither acidic nor basic. Equal concentration of H+ and OH- ions.
- Collect samples: dilute HCl, dilute NaOH, lemon juice, water, baking soda solution.
- Put a drop of universal indicator on each sample (or dip pH paper into each).
- Compare the colour with the standard pH chart and record the pH value.
| Solution | Colour | Approx. pH | Nature |
|---|---|---|---|
| Dilute HCl | Red | 1 | Strongly acidic |
| Lemon juice | Red-orange | 2-3 | Acidic |
| Pure water | Green | 7 | Neutral |
| Baking soda | Blue-green | 8-9 | Mildly basic |
| Dilute NaOH | Violet/purple | 13-14 | Strongly basic |
Importance of pH in Everyday Life
The pH value is crucial in many aspects of our daily lives, in nature, and in industry:
| Context | pH Role | Details |
|---|---|---|
| Digestive system | Stomach acid | Our stomach produces HCl (pH ~ 1.2 to 2). It helps in digestion of food and killing bacteria. Excess acid causes acidity — antacids (mild bases like Mg(OH)2) are used to neutralise it. |
| Tooth decay | pH < 5.5 | Bacteria in the mouth produce acids from sugar. When pH drops below 5.5, tooth enamel (calcium phosphate) begins to corrode. Using basic toothpaste helps neutralise the acid. |
| Bee/ant sting | Formic acid | Bee stings inject methanoic acid (formic acid). Applying baking soda (NaHCO3, a mild base) neutralises the acid and relieves pain. |
| Soil pH | Agriculture | Most plants grow best in soil pH 6-7. Too acidic soil is treated with quicklime (CaO) or slaked lime Ca(OH)2. Too basic soil may need organic matter. |
| Factory effluents | Water treatment | Factory waste must be neutralised before discharge into rivers. Acidic effluents are treated with bases, and vice versa. |
Dilution of Acids — A Safety-Critical Process
- Take about 10 mL of water in a beaker.
- Slowly add a small quantity of concentrated sulphuric acid to the water, drop by drop, while stirring continuously.
- Touch the outer wall of the beaker carefully. Note the temperature change.
The beaker becomes very hot. The process of mixing acid with water is highly exothermic.
Safety Rule: Always add acid to water, never water to acid. If water is added to concentrated acid, the enormous heat generated can cause the mixture to splash out violently, causing severe burns. When acid is added to a large volume of water, the heat is absorbed by the water, making the process safer.
Competency-Based Questions
Q1. L1 Remember A solution has pH = 7. What is its nature?
Q2. L2 Understand Arrange solutions P, Q, R, S, T in order of increasing hydrogen ion concentration. (2 marks)
Hydrogen ion concentration increases as pH decreases. So the solution with the lowest pH (P, pH 1) has the highest H+ concentration, while T (pH 14) has the lowest.
Q3. L4 Analyse Dry HCl gas does not change the colour of dry litmus paper, but moist HCl gas does. Explain why, relating your answer to the role of water. (3 marks)
Q4. L3 Apply A person is stung by a bee. The sting injects formic acid. Suggest a household remedy and explain how it works chemically. (2 marks)
Q5. L5 Evaluate A student claims: "Since glucose dissolves in water, it must produce ions like HCl does." Evaluate this claim using evidence from Activity 2.6. (3 marks)
Assertion-Reason Questions
Assertion (A): Acids produce H+(aq) ions only in aqueous solution.
Reason (R): Water molecules help in the ionisation of acid molecules by stabilising the ions formed.
Assertion (A): When pH of a solution decreases from 7 to 1, the solution becomes increasingly acidic.
Reason (R): Lower pH means higher concentration of OH- ions.
Assertion (A): While diluting an acid, acid should be added to water and not water to acid.
Reason (R): Dissolving acid in water is an exothermic process, and adding acid to water allows the large volume of water to absorb the heat safely.