This MCQ module is based on: Chemical Properties of Acids and Bases
Chemical Properties of Acids and Bases
Introduction: Acids, Bases and Their Indicators
You already know from everyday life that a lemon tastes sour and soap feels slippery. The sour taste is due to the presence of an acid, while the slippery nature of soap is because it contains a base. But tasting substances in a laboratory is extremely dangerous! So scientists use special substances called indicators to test whether a substance is acidic or basic.
| Indicator | Colour in Acid | Colour in Base |
|---|---|---|
| Litmus (blue) | Turns red | Remains blue |
| Litmus (red) | Remains red | Turns blue |
| Turmeric | Remains yellow | Turns red/brown |
| Methyl orange | Red/pink | Yellow |
| Phenolphthalein | Colourless | Pink/magenta |
2.1 Understanding the Chemical Properties of Acids and Bases
In this section, we will systematically explore how acids and bases behave when they react with metals, with each other, and with metal carbonates and bicarbonates. Each reaction reveals important chemical behaviour.
2.1.1 How Do Acids and Bases React with Metals?
- Set up the apparatus as shown in Fig 2.1. Take a few pieces of zinc granules in a test tube.
- Add about 5 mL of dilute hydrochloric acid (HCl) to the test tube.
- Observe the surface of the metal carefully for bubbles.
- Bring a burning matchstick (or candle) near the mouth of the test tube. Listen for a sound.
- Repeat the experiment using dilute sulphuric acid (H2SO4) and metals like magnesium (Mg) and iron (Fe).
Bubbles of gas are produced at the surface of the metal. When a burning matchstick is brought to the mouth of the test tube, a pop sound is heard. This confirms the gas is hydrogen (H2).
Chemical equations:
- Take a few pieces of zinc granules in a test tube and add sodium hydroxide (NaOH) solution.
- Observe for any gas evolution. Test the gas with a burning splint.
- Repeat with aluminium foil/granules instead of zinc.
Bubbles appear and the gas again burns with a pop sound, confirming it is hydrogen.
Chemical equations:
Sodium zincate
Sodium aluminate
Conclusion: Both acids and certain bases react with metals to produce hydrogen gas. However, not all metals react with bases — only amphoteric metals like zinc and aluminium do.2.1.2 How Do Acids and Bases React with Each Other?
- Take about 2 mL of NaOH solution in a test tube and add a few drops of phenolphthalein indicator. The solution turns pink.
- Now add dilute HCl drop by drop while swirling the tube.
- Continue until the pink colour just disappears. The solution is now neutral.
- Touch the bottom of the test tube — you will feel warmth.
The pink colour disappears when enough HCl is added, indicating the base has been fully neutralised. The test tube feels warm because the reaction is exothermic (releases heat).
Chemical equation:
This reaction is called a neutralisation reaction. The salt produced (NaCl) and water are the products. Energy is released in the form of heat.
- Take a small quantity of copper oxide (CuO) — a black powder — in a beaker.
- Add dilute hydrochloric acid slowly while stirring.
- Observe the colour change of the solution.
The black copper oxide dissolves and the solution turns blue-green, which is the colour of copper chloride (CuCl2) solution.
This confirms that metallic oxides are basic in nature — they react with acids just like bases do, producing a salt and water.
2.1.3 How Do Metal Carbonates and Bicarbonates React with Acids?
- Set up the apparatus as shown in Fig 2.3. Take a test tube with sodium carbonate (Na2CO3) or sodium bicarbonate (NaHCO3).
- Add dilute hydrochloric acid to it.
- Pass the gas produced through freshly prepared lime water — Ca(OH)2 solution.
- Observe what happens to the lime water.
Brisk effervescence occurs. The gas turns the lime water milky, confirming it is carbon dioxide (CO2).
Chemical equations:
The white precipitate of calcium carbonate (CaCO3) makes the lime water appear milky. This is the standard test for carbon dioxide gas.
Similarly, when limestone (calcium carbonate, CaCO3) reacts with dilute hydrochloric acid:
- Metal + Acid → Salt + Hydrogen gas (H2)
- Base + Metal → Salt + Hydrogen gas (for Zn, Al)
- Acid + Base → Salt + Water (neutralisation)
- Acid + Metal carbonate/bicarbonate → Salt + Water + CO2
- Acid + Metal oxide → Salt + Water
Competency-Based Questions
Q1. L1 Remember What is the general reaction when an acid reacts with a metal?
Q2. L2 Understand In Tube C, the gas turned lime water milky. Write the balanced equation for the reaction of Na2CO3 with dilute H2SO4. Identify the gas. (2 marks)
\(\text{Na}_2\text{CO}_3(s) + \text{H}_2\text{SO}_4(aq) \rightarrow \text{Na}_2\text{SO}_4(aq) + \text{H}_2\text{O}(l) + \text{CO}_2(g)\uparrow\)
The gas produced is carbon dioxide (CO2), which turns lime water milky by forming insoluble calcium carbonate: Ca(OH)2 + CO2 → CaCO3↓ + H2O.
Q3. L4 Analyse Both Tube A and Tube B produce the same gas when tested with a burning splint. What does this tell us about the reaction of bases with metals? (3 marks)
Q4. L3 Apply A student added dilute HCl to baking soda (NaHCO3) and passed the resulting gas into lime water. Write two balanced equations for: (i) the reaction of NaHCO3 with HCl, and (ii) the reaction of CO2 with lime water. (3 marks)
(i) \(\text{NaHCO}_3(s) + \text{HCl}(aq) \rightarrow \text{NaCl}(aq) + \text{H}_2\text{O}(l) + \text{CO}_2(g)\uparrow\)
(ii) \(\text{Ca(OH)}_2(aq) + \text{CO}_2(g) \rightarrow \text{CaCO}_3(s)\downarrow + \text{H}_2\text{O}(l)\)
The white precipitate of CaCO3 causes the lime water to appear milky.
Q5. L5 Evaluate Rahul claims: "All metals react with NaOH to produce hydrogen gas." Is this statement correct? Justify your answer with examples. (3 marks)
Assertion-Reason Questions
Assertion (A): When zinc reacts with dilute hydrochloric acid, zinc chloride and hydrogen gas are formed.
Reason (R): Hydrogen gas burns with a pop sound when a burning splint is brought near it.
Assertion (A): When CO2 gas is passed through lime water, it turns milky.
Reason (R): CO2 reacts with calcium hydroxide to form insoluble calcium carbonate.
Assertion (A): Neutralisation is an exothermic reaction.
Reason (R): In a neutralisation reaction, an acid and a base react to form salt and water with the release of heat.