This MCQ module is based on: Chemical Effects of Electric Current
Chemical Effects of Electric Current
Probe and Ponder
Your torch needs a fresh pair of dry cells every few months. Your phone survives for years on the same battery — you just plug it in every night. What's the difference? And is there really any chemistry happening inside a battery?
- Why can some cells be recharged while others must be thrown away?
- What makes a lemon conduct electricity while pure water does not?
- How does a silver coating end up on a cheap iron spoon?
- Where do millions of old batteries go every year — and is it a problem?
4.9 Types of Cells — Primary and Secondary
All electric cells store energy as chemicals and release it as electricity. But they fall into two big families.
A. Primary Cells — Single-Use
Once the chemicals inside are used up, the cell is dead forever. You throw it away.
- Dry cell (Zn–C): the little AA or AAA cell in your TV remote.
- Alkaline cell: longer-lasting version used in toys and torches.
- Mercury / button cell: tiny cells in watches and hearing aids.
B. Secondary Cells — Rechargeable
The chemical reaction inside is reversible. Push current backwards through the cell and it gets recharged.
- Lead-acid battery: starts the engine of every car and motorbike.
- Lithium-ion (Li-ion) cell: phones, laptops, electric cars — light and long-lasting.
- Nickel-metal hydride (NiMH): cameras, toys, some cordless devices.
4.10 Chemical Effect of Electric Current
Current does more than make heat and magnetism — it also causes chemical changes in some liquids. This is called the chemical effect of current.
- Take a lemon and squeeze the juice into a small glass.
- Fix two iron nails as electrodes, dipped in the juice but not touching.
- Connect the nails to an LED and a 1.5 V cell through a switch.
- Switch ON — observe the LED.
- Repeat the same setup with pure (distilled) water instead of lemon juice.
Electrolytes and Non-Electrolytes
| Electrolytes (conduct) | Non-electrolytes (don't conduct) |
|---|---|
| Lemon juice, vinegar, common salt solution, dilute acids, bases, salt water | Sugar solution, alcohol, distilled water, oil |
| Why? They split into free ions (+ and −) that carry charge. | Why? They do not produce free ions in solution. |
Electrolysis — Chemistry by Current
When current is passed through an electrolyte, chemical changes happen at the two electrodes. For example, passing current through water (with a little acid added) splits it into hydrogen and oxygen gas:
Electroplating — Giving Objects a Metal Coat
Electroplating is the use of electrolysis to deposit a thin metal coating on another object. It is used to protect iron from rust (zinc-plating or chromium-plating), and to make cheap objects look shiny (silver/gold plating).
Big Industrial Uses of Electrolysis
4.11 Can Batteries Be Recharged?
Here's the golden rule:
Secondary cells CAN be recharged. The chemical reaction is reversible — pushing current in the opposite direction restores the chemicals.
Trying to recharge a primary cell is dangerous — it can leak, heat up, or even explode.
How to Check If a Cell is Dead
A simple test: connect the suspect cell to an LED (through a matching resistor) or a small bulb.
- If the LED / bulb glows → cell is still good.
- If nothing happens → cell is dead.
The E-Waste Problem
India generates millions of used cells every year. Most contain toxic heavy metals such as mercury, lead, cadmium, and nickel. If dumped in ordinary waste, they leak into soil and water — poisoning plants, animals, and people.
The Lithium Question
Every phone, laptop, and electric scooter runs on lithium-ion cells. Demand for lithium is exploding. But mining it uses huge amounts of water and damages fragile ecosystems. Scientists in India and abroad are working on:
- Batteries that use cheaper, abundant metals like sodium or iron.
- Better recycling — recovering lithium from old batteries.
- Longer-lasting cells so we make fewer.
🎯 Try It: Can It Be Recharged? L2 Understand
Click each item to send it to the correct column.
♻️ Rechargeable
🗑️ Single-use
📋 Competency-Based Questions
Q1. L2 Understand In which liquid(s) will the LED definitely glow?
Q2. L1 Remember Give two examples each of (a) primary cells and (b) secondary cells. (Short Answer)
Q3. L3 Apply Fill in the blanks: In electroplating, the object to be coated is connected to the ______ terminal, while a pure plate of the coating metal is connected to the ______ terminal.
Q4. L4 Analyse Why should we never throw old batteries into ordinary household garbage? (3 marks)
Q5. L6 Create HOT: Suggest one way India can reduce its dependence on lithium imports. (2 marks)
🔗 Assertion–Reason Questions
Assertion (A): Sugar solution does not conduct electricity.
Reason (R): Sugar does not dissociate into ions when dissolved in water.
Assertion (A): A car battery is a secondary cell.
Reason (R): Chemical reactions in a car's lead-acid battery are reversible, allowing it to be recharged.
Assertion (A): A layer of chromium is deposited on iron to prevent rusting.
Reason (R): Chromium reacts vigorously with oxygen in the air.