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Atoms, Molecules and Ions

🎓 Class 9 Science CBSE Theory Ch 9 — Atomic Foundations of Matter ⏱ ~16 min
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Introduction: From Atoms to the Stuff We See

If atoms are so unimaginably tiny — far too small to be seen even with a powerful optical microscope — how does a chemist talk about their masses? And why are the substances we actually meet in daily life mostly not single atoms but groups of atoms stuck together? In this part we shall learn how atoms are weighed on a relative scale, how they bind into molecules, and how some atoms become charged species called ions. Finally, we shall use these ideas to build the chemical formula of any compound using a simple criss-cross trick.

9.4 Atomic Mass

An atom of hydrogen has a mass of roughly \(1.66 \times 10^{-24}\) g. Such a clumsy number is awkward to use, so chemists adopt a relative scale. By international agreement, one atom of carbon-12 is assigned a mass of exactly 12 atomic mass units (u). Every other atom is then weighed by comparison.

Atomic mass unit (u). One atomic mass unit equals one-twelfth the mass of a single carbon-12 atom: \(1\,\text{u} = \dfrac{1}{12}\)(mass of one C-12 atom) \(\approx 1.66 \times 10^{-24}\) g.

The atomic mass of an element therefore tells you how heavy one atom of that element is compared to one-twelfth of a carbon-12 atom.

ElementSymbolAtomic mass (u)
HydrogenH1
CarbonC12
NitrogenN14
OxygenO16
SodiumNa23
MagnesiumMg24
SulphurS32
ChlorineCl35.5
CalciumCa40
Atomic Mass — Relative to ¹²C Carbon-12 12 u (reference) H = 1 u O = 16 u One H atom is \"1/12 as heavy\" as one C-12 atom; one O atom is 16/12 as heavy.
Fig 9.4: Carbon-12 sets the standard. Every other atomic mass is its mass relative to one-twelfth of a C-12 atom.

9.5 Molecules

Most elements and all compounds exist as molecules rather than free atoms. A molecule is the smallest particle of an element or a compound that can lead an independent existence and still show all the chemical properties of that substance.

A. Molecules of Elements

When the atoms forming a molecule belong to the same element, we call it a molecule of an element. Many non-metals exist this way at room temperature.

ElementMoleculeAtomicity
Helium, Argon, NeonHe, Ar, NeMono-atomic (1)
Hydrogen, Oxygen, Nitrogen, ChlorineH2, O2, N2, Cl2Di-atomic (2)
OzoneO3Tri-atomic (3)
PhosphorusP4Tetra-atomic (4)
SulphurS8Octa-atomic (8)
Atomicity. The number of atoms present in one molecule of a substance is called its atomicity.

B. Molecules of Compounds

When atoms of different elements join together in a fixed whole-number ratio, the result is a molecule of a compound.

CompoundFormulaCombining atoms (ratio)
WaterH2OH : O = 2 : 1
AmmoniaNH3N : H = 1 : 3
Carbon dioxideCO2C : O = 1 : 2
Hydrogen chlorideHClH : Cl = 1 : 1
MethaneCH4C : H = 1 : 4
Molecules of Elements Molecules of Compounds O₂ O₃ (ozone) P₄ S₈ (ring) H₂O NH₃ CO₂ HCl
Fig 9.5: Molecules of elements (O₂, O₃, P₄, S₈) versus molecules of compounds (H₂O, NH₃, CO₂, HCl).

Activity — Counting atoms in a molecule

Activity 9.2 — Find the AtomicityL2 Understand
Predict first: How many atoms are present, in total, in one molecule each of HNO₃, H₂SO₄ and Ca(OH)₂?
  1. Write down the formula clearly.
  2. For each element symbol, note the subscript (the small number written after it). No subscript means 1.
  3. If a group is enclosed in brackets followed by a subscript, multiply every atom inside the brackets by that subscript.
  4. Add up the counts of all atoms.
HNO3: H = 1, N = 1, O = 3 → atomicity = 5.
H2SO4: H = 2, S = 1, O = 4 → atomicity = 7.
Ca(OH)2: Ca = 1, O = 1×2 = 2, H = 1×2 = 2 → atomicity = 5.
Tip: The subscript outside the bracket multiplies every atom inside.

9.6 Ions — Charged Particles

Atoms are electrically neutral. But during many reactions, particularly between metals and non-metals, atoms can lose or gain electrons and become charged. A charged atom (or group of atoms) is called an ion.

Cations (positive ions)

When an atom loses electrons, it has more protons than electrons and so carries a net positive charge. Such an ion is called a cation. Metals usually form cations.

  • Sodium loses 1 electron → Na+
  • Magnesium loses 2 electrons → Mg2+
  • Aluminium loses 3 electrons → Al3+

Anions (negative ions)

When an atom gains electrons, it has more electrons than protons and so carries a net negative charge. Such an ion is called an anion. Non-metals usually form anions.

  • Chlorine gains 1 electron → Cl
  • Oxygen gains 2 electrons → O2−
  • Hydroxide group: OH; sulphate group: SO42−

⚛️ Ion Builder — Click each particle L1 Remember

Click each circle — Na, Na⁺, Cl, Cl⁻ — to recall what each particle is, how many protons/electrons it has and which charge it carries.

Formation of Ions Na – 1 e⁻ Na⁺ Cation (positive) Cl + 1 e⁻ Cl⁻ Anion (negative)
Fig 9.6: A metal atom loses electrons to form a cation; a non-metal atom gains electrons to form an anion.
Click Na · Na⁺ · Cl · Cl⁻ above to recall the name, charge and electron count of each particle.

Polyatomic ions

Some ions are made of a tightly bonded group of atoms that carries a net charge. Common examples are hydroxide (OH), nitrate (NO3), carbonate (CO32−), sulphate (SO42−) and ammonium (NH4+).

9.7 Writing a Chemical Formula — Criss-Cross Method

A chemical formula tells us which atoms (or ions) are present in one formula unit and in what numbers. The simplest way to construct it is the criss-cross method.

Criss-Cross Rule. Write the cation first with its valency on top. Write the anion next to it, also with its valency on top. Then exchange (criss-cross) the magnitudes of the valencies and write each as a subscript on the other ion. Finally simplify the subscripts to the smallest whole numbers. Any subscript of 1 is not written.
Criss-Cross Method — Aluminium Oxide Al +3 O −2 criss-cross subscript = 2 subscript = 3 Al₂O₃ aluminium oxide
Fig 9.7: Cross the magnitudes of the valencies to obtain the subscripts of the formula.

Worked examples

(i) Sodium chloride: Na+1   Cl−1 → Na1Cl1 = NaCl.
(ii) Calcium chloride: Ca+2   Cl−1 → Ca1Cl2 = CaCl2.
(iii) Aluminium sulphate: Al+3   SO4−2 → Al2(SO4)3  (brackets needed because SO4 is a polyatomic ion).
(iv) Ammonium nitrate: NH4+1   NO3−1NH4NO3.
(v) Magnesium hydroxide: Mg+2   OH−1Mg(OH)2.

Quick Recap

TermMeaning
Atomic mass (u)Mass of one atom relative to 1/12 of a C-12 atom.
MoleculeSmallest particle of an element/compound that can exist independently.
AtomicityNumber of atoms in one molecule.
CationPositive ion — formed by loss of electrons (mostly metals).
AnionNegative ion — formed by gain of electrons (mostly non-metals).
Chemical formulaSymbolic representation of one formula unit of a compound.

Competency-Based Questions

A bottle in the laboratory is labelled "Aluminium sulphate, Al2(SO4)3". A student is asked to interpret what this formula tells about the substance. The atomic masses are Al = 27, S = 32, O = 16.
Q1. Find the total number of atoms in one formula unit of Al2(SO4)3. L2
  • (a) 9
  • (b) 14
  • (c) 17
  • (d) 20
(c) 17. Al = 2; S = 1×3 = 3; O = 4×3 = 12. Total = 2 + 3 + 12 = 17 atoms.
Q2. Identify the cation and the anion in Al2(SO4)3 and state their charges. L1
Cation: Al3+ (charge +3, formed by aluminium losing 3 electrons). Anion: SO42− (charge −2, polyatomic sulphate group).
Q3. Verify, using the criss-cross method, that aluminium and sulphate combine in the ratio 2 : 3. L3
Charges are +3 (Al) and −2 (SO4). Cross the magnitudes: subscript of Al = 2, subscript of SO4 = 3 → Al2(SO4)3. The cross-charge cancels: 2(+3) + 3(−2) = +6 − 6 = 0, so the formula is electrically neutral. ✓
Q4. State whether the following is True or False with reason: "Argon and helium are mono-atomic, so their molecules and atoms are the same." L2
True. Noble gases consist of single, chemically inert atoms; the smallest independent particle is just one atom, so atomicity = 1 and "atom" and "molecule" coincide.
Q5. Phosphorus exists as P4 while sulphur exists as S8. State which has higher atomicity and explain what atomicity means. L1
Sulphur has the higher atomicity (8 versus 4). Atomicity is the number of atoms present in a single molecule of the substance.

Assertion–Reason Questions

Options: (A) Both A and R are true and R is the correct explanation of A. (B) Both true but R is not the correct explanation. (C) A true, R false. (D) A false, R true.

A: Sodium readily forms Na⁺ during chemical reactions.
R: Sodium has one electron in its outermost shell which it can lose easily to attain a stable octet.
(A) Both statements are true and R is the correct explanation. Losing one electron leaves Na with an inert-gas-like configuration of neon.
A: The chemical formula of magnesium chloride is MgCl2.
R: Magnesium has a valency of +2 and chlorine has a valency of −1, so two chloride ions are required to balance one magnesium ion.
(A) Both true and R correctly explains A. The criss-cross method gives Mg1Cl2 = MgCl2.
A: The atomic mass of an element is expressed in grams.
R: Atomic masses are measured relative to 1/12 of the mass of a carbon-12 atom and are expressed in atomic mass units (u).
(D) Assertion is false — atomic mass is given in unified atomic mass units (u), not grams. Reason is true and is the correct definition of u.
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