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Chemical Effects of Electric Current

🎓 Class 8 Science CBSE Theory Ch 4 — Materials: Metals and Non-Metals ⏱ ~28 min
🌐 Language: [gtranslate]

This MCQ module is based on: Chemical Effects of Electric Current

[myaischool_lt_science_assessment grade_level="class_8" science_domain="chemistry" difficulty="basic"]

Probe and Ponder

Your torch needs a fresh pair of dry cells every few months. Your phone survives for years on the same battery — you just plug it in every night. What's the difference? And is there really any chemistry happening inside a battery?

  • Why can some cells be recharged while others must be thrown away?
  • What makes a lemon conduct electricity while pure water does not?
  • How does a silver coating end up on a cheap iron spoon?
  • Where do millions of old batteries go every year — and is it a problem?

4.9 Types of Cells — Primary and Secondary

All electric cells store energy as chemicals and release it as electricity. But they fall into two big families.

A. Primary Cells — Single-Use

Once the chemicals inside are used up, the cell is dead forever. You throw it away.

  • Dry cell (Zn–C): the little AA or AAA cell in your TV remote.
  • Alkaline cell: longer-lasting version used in toys and torches.
  • Mercury / button cell: tiny cells in watches and hearing aids.

B. Secondary Cells — Rechargeable

The chemical reaction inside is reversible. Push current backwards through the cell and it gets recharged.

  • Lead-acid battery: starts the engine of every car and motorbike.
  • Lithium-ion (Li-ion) cell: phones, laptops, electric cars — light and long-lasting.
  • Nickel-metal hydride (NiMH): cameras, toys, some cordless devices.
Primary vs Secondary Cells Primary (dry cell) Zn-C, 1.5 V × cannot recharge Secondary (Li-ion) Li-ion 3.7 V, phone battery ✓ can recharge vs
Fig 4.11 — Primary cells are throwaway; secondary cells come back to life after recharging.
Common idea: In every cell, chemical energy is converted into electrical energy. When recharged, electrical energy pushes the chemistry backwards so it can run again.

4.10 Chemical Effect of Electric Current

Current does more than make heat and magnetism — it also causes chemical changes in some liquids. This is called the chemical effect of current.

🔬 Activity 4.11 — Can a Lemon Light an LED?L3 Apply
🤔 Predict first: Which liquid will allow current to flow and light up an LED — lemon juice or distilled water?
  1. Take a lemon and squeeze the juice into a small glass.
  2. Fix two iron nails as electrodes, dipped in the juice but not touching.
  3. Connect the nails to an LED and a 1.5 V cell through a switch.
  4. Switch ON — observe the LED.
  5. Repeat the same setup with pure (distilled) water instead of lemon juice.
Observation: With lemon juice the LED glows — current flows. With distilled water the LED does NOT glow — no current. Lemon juice contains acids that split into charged particles called ions, which carry the current. Pure water has almost no ions.

Electrolytes and Non-Electrolytes

Electrolytes (conduct)Non-electrolytes (don't conduct)
Lemon juice, vinegar, common salt solution, dilute acids, bases, salt waterSugar solution, alcohol, distilled water, oil
Why? They split into free ions (+ and −) that carry charge.Why? They do not produce free ions in solution.

Electrolysis — Chemistry by Current

When current is passed through an electrolyte, chemical changes happen at the two electrodes. For example, passing current through water (with a little acid added) splits it into hydrogen and oxygen gas:

2 H₂O (water) → 2 H₂ (at cathode) + O₂ (at anode)
Electrolysis of Water Acidic water (electrolyte) + H₂ O₂ Battery
Fig 4.12 — Current through acidic water produces twice as much H₂ as O₂ (by volume).

Electroplating — Giving Objects a Metal Coat

Electroplating is the use of electrolysis to deposit a thin metal coating on another object. It is used to protect iron from rust (zinc-plating or chromium-plating), and to make cheap objects look shiny (silver/gold plating).

Electroplating — Copper onto an Iron Spoon CuSO₄ solution (electrolyte) + Copper plate Iron spoon Cu²⁺ ions
Fig 4.13 — Copper ions travel from the copper plate to the iron spoon and coat it evenly.

Big Industrial Uses of Electrolysis

🛡️
Rust-proofing
Iron items coated with zinc (galvanising) or chromium to prevent rusting.
💧
Hydrogen fuel
Electrolysis of water produces pure hydrogen — a clean, green fuel of the future.
⚗️
Metal extraction
Aluminium and sodium are extracted from their ores only by electrolysis.
Decorative plating
Cheap jewellery is silver- or gold-plated to look like the real thing.

4.11 Can Batteries Be Recharged?

Here's the golden rule:

Primary cells CANNOT be recharged. The chemical reaction inside them is one-way. Once the chemicals are used up, the cell is dead.

Secondary cells CAN be recharged. The chemical reaction is reversible — pushing current in the opposite direction restores the chemicals.

Trying to recharge a primary cell is dangerous — it can leak, heat up, or even explode.

How to Check If a Cell is Dead

A simple test: connect the suspect cell to an LED (through a matching resistor) or a small bulb.

  • If the LED / bulb glows → cell is still good.
  • If nothing happens → cell is dead.

The E-Waste Problem

India generates millions of used cells every year. Most contain toxic heavy metals such as mercury, lead, cadmium, and nickel. If dumped in ordinary waste, they leak into soil and water — poisoning plants, animals, and people.

Dispose of Batteries Safely! E-WASTE ONLY ! TOXIC METALS Pb, Hg, Cd, Ni
Fig 4.14 — Old cells must go to a dedicated e-waste bin or recycling centre.
India's response: Under the E-Waste Management Rules, manufacturers must collect old batteries for recycling. Look for e-waste collection boxes in big stores and schools. Never throw cells into regular dustbins or burn them.

The Lithium Question

Every phone, laptop, and electric scooter runs on lithium-ion cells. Demand for lithium is exploding. But mining it uses huge amounts of water and damages fragile ecosystems. Scientists in India and abroad are working on:

  • Batteries that use cheaper, abundant metals like sodium or iron.
  • Better recycling — recovering lithium from old batteries.
  • Longer-lasting cells so we make fewer.

🎯 Try It: Can It Be Recharged? L2 Understand

Click each item to send it to the correct column.

AA dry cell Phone Li-ion battery Button (watch) cell Car lead-acid battery Laptop battery Zn-C remote cell NiMH camera battery Alkaline torch cell

♻️ Rechargeable

🗑️ Single-use

📋 Competency-Based Questions

Ravi's science club runs an experiment. They dip two electrodes in three different liquids (lemon juice, sugar solution, and tap water) one by one. An LED is connected in series with each setup and a 1.5 V cell. They note when the LED glows.

Q1. L2 Understand In which liquid(s) will the LED definitely glow?

  • A. Only sugar solution
  • B. Lemon juice and tap water
  • C. Only lemon juice
  • D. All three
Answer: B. Lemon juice (acid) has strong ions; tap water has some dissolved salts/minerals and usually conducts weakly. Sugar solution is a non-electrolyte — no ions.

Q2. L1 Remember Give two examples each of (a) primary cells and (b) secondary cells. (Short Answer)

Answer: (a) Primary: dry (Zn-C) cell, alkaline cell, mercury/button cell. (b) Secondary: lead-acid battery (cars), lithium-ion cell (phones), NiMH cell (cameras).

Q3. L3 Apply Fill in the blanks: In electroplating, the object to be coated is connected to the ______ terminal, while a pure plate of the coating metal is connected to the ______ terminal.

Answer: negative (cathode) ; positive (anode).

Q4. L4 Analyse Why should we never throw old batteries into ordinary household garbage? (3 marks)

Answer: Old cells contain heavy metals such as mercury, lead, cadmium, and nickel. In landfills, these metals leak out into soil and groundwater. They are toxic — they poison plants, animals, and people who drink contaminated water. Batteries must be dropped into e-waste bins or given to certified recyclers.

Q5. L6 Create HOT: Suggest one way India can reduce its dependence on lithium imports. (2 marks)

Hint: Any of — (i) invest in recycling facilities to recover lithium from old batteries; (ii) research and produce sodium-ion or iron-based batteries using abundant Indian minerals; (iii) encourage longer-lasting battery designs and shared/rented battery pools for electric vehicles.

🔗 Assertion–Reason Questions

Assertion (A): Sugar solution does not conduct electricity.

Reason (R): Sugar does not dissociate into ions when dissolved in water.

  • A. Both A and R are true, and R correctly explains A.
  • B. Both A and R are true, but R does not explain A.
  • C. A is true, R is false.
  • D. A is false, R is true.
Answer: A. No free ions → no charge carriers → no current flow.

Assertion (A): A car battery is a secondary cell.

Reason (R): Chemical reactions in a car's lead-acid battery are reversible, allowing it to be recharged.

  • A. Both A and R are true, and R correctly explains A.
  • B. Both A and R are true, but R does not explain A.
  • C. A is true, R is false.
  • D. A is false, R is true.
Answer: A. Reversibility of the chemistry is the exact reason it is classed as a secondary (rechargeable) cell.

Assertion (A): A layer of chromium is deposited on iron to prevent rusting.

Reason (R): Chromium reacts vigorously with oxygen in the air.

  • A. Both A and R are true, and R correctly explains A.
  • B. Both A and R are true, but R does not explain A.
  • C. A is true, R is false.
  • D. A is false, R is true.
Answer: C. A is true — chromium plating does protect iron. R is false — chromium actually forms a very thin, stable oxide layer that blocks further reaction, which is why it protects well.

💡 Did You Know?
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