This MCQ module is based on: Atoms, Molecules and Ions
Atoms, Molecules and Ions
This assessment will be based on: Atoms, Molecules and Ions
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Introduction: From Atoms to the Stuff We See
If atoms are so unimaginably tiny — far too small to be seen even with a powerful optical microscope — how does a chemist talk about their masses? And why are the substances we actually meet in daily life mostly not single atoms but groups of atoms stuck together? In this part we shall learn how atoms are weighed on a relative scale, how they bind into molecules, and how some atoms become charged species called ions. Finally, we shall use these ideas to build the chemical formula of any compound using a simple criss-cross trick.
9.4 Atomic Mass
An atom of hydrogen has a mass of roughly \(1.66 \times 10^{-24}\) g. Such a clumsy number is awkward to use, so chemists adopt a relative scale. By international agreement, one atom of carbon-12 is assigned a mass of exactly 12 atomic mass units (u). Every other atom is then weighed by comparison.
The atomic mass of an element therefore tells you how heavy one atom of that element is compared to one-twelfth of a carbon-12 atom.
| Element | Symbol | Atomic mass (u) |
|---|---|---|
| Hydrogen | H | 1 |
| Carbon | C | 12 |
| Nitrogen | N | 14 |
| Oxygen | O | 16 |
| Sodium | Na | 23 |
| Magnesium | Mg | 24 |
| Sulphur | S | 32 |
| Chlorine | Cl | 35.5 |
| Calcium | Ca | 40 |
9.5 Molecules
Most elements and all compounds exist as molecules rather than free atoms. A molecule is the smallest particle of an element or a compound that can lead an independent existence and still show all the chemical properties of that substance.
A. Molecules of Elements
When the atoms forming a molecule belong to the same element, we call it a molecule of an element. Many non-metals exist this way at room temperature.
| Element | Molecule | Atomicity |
|---|---|---|
| Helium, Argon, Neon | He, Ar, Ne | Mono-atomic (1) |
| Hydrogen, Oxygen, Nitrogen, Chlorine | H2, O2, N2, Cl2 | Di-atomic (2) |
| Ozone | O3 | Tri-atomic (3) |
| Phosphorus | P4 | Tetra-atomic (4) |
| Sulphur | S8 | Octa-atomic (8) |
B. Molecules of Compounds
When atoms of different elements join together in a fixed whole-number ratio, the result is a molecule of a compound.
| Compound | Formula | Combining atoms (ratio) |
|---|---|---|
| Water | H2O | H : O = 2 : 1 |
| Ammonia | NH3 | N : H = 1 : 3 |
| Carbon dioxide | CO2 | C : O = 1 : 2 |
| Hydrogen chloride | HCl | H : Cl = 1 : 1 |
| Methane | CH4 | C : H = 1 : 4 |
Activity — Counting atoms in a molecule
- Write down the formula clearly.
- For each element symbol, note the subscript (the small number written after it). No subscript means 1.
- If a group is enclosed in brackets followed by a subscript, multiply every atom inside the brackets by that subscript.
- Add up the counts of all atoms.
H2SO4: H = 2, S = 1, O = 4 → atomicity = 7.
Ca(OH)2: Ca = 1, O = 1×2 = 2, H = 1×2 = 2 → atomicity = 5.
Tip: The subscript outside the bracket multiplies every atom inside.
9.6 Ions — Charged Particles
Atoms are electrically neutral. But during many reactions, particularly between metals and non-metals, atoms can lose or gain electrons and become charged. A charged atom (or group of atoms) is called an ion.
Cations (positive ions)
When an atom loses electrons, it has more protons than electrons and so carries a net positive charge. Such an ion is called a cation. Metals usually form cations.
- Sodium loses 1 electron → Na+
- Magnesium loses 2 electrons → Mg2+
- Aluminium loses 3 electrons → Al3+
Anions (negative ions)
When an atom gains electrons, it has more electrons than protons and so carries a net negative charge. Such an ion is called an anion. Non-metals usually form anions.
- Chlorine gains 1 electron → Cl−
- Oxygen gains 2 electrons → O2−
- Hydroxide group: OH−; sulphate group: SO42−
⚛️ Ion Builder — Click each particle L1 Remember
Click each circle — Na, Na⁺, Cl, Cl⁻ — to recall what each particle is, how many protons/electrons it has and which charge it carries.
Polyatomic ions
Some ions are made of a tightly bonded group of atoms that carries a net charge. Common examples are hydroxide (OH−), nitrate (NO3−), carbonate (CO32−), sulphate (SO42−) and ammonium (NH4+).
9.7 Writing a Chemical Formula — Criss-Cross Method
A chemical formula tells us which atoms (or ions) are present in one formula unit and in what numbers. The simplest way to construct it is the criss-cross method.
Worked examples
(ii) Calcium chloride: Ca+2 Cl−1 → Ca1Cl2 = CaCl2.
(iii) Aluminium sulphate: Al+3 SO4−2 → Al2(SO4)3 (brackets needed because SO4 is a polyatomic ion).
(iv) Ammonium nitrate: NH4+1 NO3−1 → NH4NO3.
(v) Magnesium hydroxide: Mg+2 OH−1 → Mg(OH)2.
Quick Recap
| Term | Meaning |
|---|---|
| Atomic mass (u) | Mass of one atom relative to 1/12 of a C-12 atom. |
| Molecule | Smallest particle of an element/compound that can exist independently. |
| Atomicity | Number of atoms in one molecule. |
| Cation | Positive ion — formed by loss of electrons (mostly metals). |
| Anion | Negative ion — formed by gain of electrons (mostly non-metals). |
| Chemical formula | Symbolic representation of one formula unit of a compound. |
Competency-Based Questions
Assertion–Reason Questions
Options: (A) Both A and R are true and R is the correct explanation of A. (B) Both true but R is not the correct explanation. (C) A true, R false. (D) A false, R true.