This MCQ module is based on: Temperature Thermal Expansion
Temperature Thermal Expansion
This assessment will be based on: Temperature Thermal Expansion
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Temperature Thermal Expansion
10.1 Introduction: Heat & Temperature in Daily Life
A kettle of boiling water feels much "hotter" than a glass of iced water. Common sense links this hotness with a quantity called temperature. In physics we sharpen this idea: temperature decides the direction in which heat flows. Heat is energy in transit; temperature is the property that controls that transit.
This first part of Chapter 10 covers (i) what temperature really means, (ii) how thermometers measure it, (iii) the different thermometric scales (Celsius, Fahrenheit, Kelvin), (iv) the constant-volume gas thermometer that leads us to absolute zero, and (v) thermal expansion — how solids, liquids and gases enlarge when heated.
10.2 Temperature and Heat
Heat is the form of energy transferred between two (or more) bodies (or system and surroundings) by virtue of temperature difference. The SI unit of heat is the joule (J). The cgs unit is the calorie (cal); 1 cal = 4.186 J.
10.3 Measurement of Temperature
Any physical property that varies smoothly and reproducibly with temperature can serve as a thermometric property. Examples are: the volume of a liquid (mercury, alcohol thermometer), the pressure of a fixed mass of gas at constant volume, the resistance of a platinum wire (resistance thermometer), or the colour of a hot body (pyrometer).
10.3.1 The Celsius and Fahrenheit Scales
Most thermometers used in everyday life are liquid-in-glass thermometers, calibrated against two reference points:
- Ice point (lower fixed point): melting point of pure ice at 1 atm.
- Steam point (upper fixed point): boiling point of pure water at 1 atm.
On the Celsius scale these are 0 °C and 100 °C, divided into 100 equal parts. On the Fahrenheit scale they are 32 °F and 212 °F, divided into 180 parts. The conversion is:
10.3.2 The Constant-Volume Gas Thermometer
Real-gas thermometers are far more reproducible than mercury thermometers. The constant-volume gas thermometer (Fig 10.2) keeps a fixed amount of gas in a bulb at constant volume; the gas pressure \(P\) becomes the thermometric property. Different gases (H₂, He, N₂, O₂) all give straight-line P–T graphs that, when extrapolated backwards, meet the temperature axis at the same intercept.
10.3.3 Absolute (Kelvin) Scale
The intercept −273.15 °C is therefore a natural lower limit of temperature: absolute zero. Lord Kelvin defined a new scale starting there, with the same step size as Celsius. The kelvin (K) is now the SI unit of temperature.
10.4 Ideal Gas Equation and Absolute Temperature
For a fixed mass of an ideal gas the experimental laws of Boyle, Charles and Avogadro combine into the single relation:
For a constant amount of gas: \(\dfrac{P_1V_1}{T_1}=\dfrac{P_2V_2}{T_2}\). At low pressures real gases obey this relation closely; at high pressures and low temperatures deviations appear (covered in Chapter 12 — Kinetic Theory).
10.5 Thermal Expansion
Most substances expand on heating and contract on cooling. The microscopic reason: at higher temperature the atoms vibrate with larger amplitude about their mean positions, and because the inter-atomic potential is asymmetric, the mean separation between atoms increases.
10.5.1 Linear Expansion
Consider a rod of length \(L\) at temperature \(T\). When heated by \(\Delta T\) its length increases by \(\Delta L\). Experiment shows \(\Delta L \propto L\) and \(\Delta L \propto \Delta T\):
| Material | αL (×10⁻⁶ K⁻¹) | Material | αL (×10⁻⁶ K⁻¹) |
|---|---|---|---|
| Aluminium | 23 | Steel | 11 |
| Copper | 17 | Glass (ordinary) | 9 |
| Brass | 19 | Glass (Pyrex) | 3.2 |
| Iron | 12 | Invar (Fe-Ni alloy) | 0.9 |
10.5.2 Area (Superficial) Expansion
For an isotropic plate of area \(A\) heated by \(\Delta T\):
Derivation: a square plate of side \(L\) has area \(A = L^2\). After heating, side becomes \(L(1+\alpha_L\Delta T)\). New area \(A' = L^2(1+\alpha_L\Delta T)^2 \approx L^2(1 + 2\alpha_L \Delta T)\) for small \(\alpha_L \Delta T\). So \(\Delta A/A = 2\alpha_L\Delta T\).
10.5.3 Volume (Cubical) Expansion
For an isotropic solid of volume \(V\):
For liquids and gases there is only volume expansion (no fixed shape). The coefficient \(\alpha_V\) of liquids is about 10× that of solids; gases expand even more — for an ideal gas at constant pressure, \(\alpha_V = 1/T \approx 3.66\times 10^{-3}\) K\(^{-1}\) at 273 K.
10.5.4 Anomalous Expansion of Water
Most substances expand monotonically. Water is an oddity: between 0 °C and 4 °C its volume decreases with rising temperature; above 4 °C it expands normally. So water is densest at 4 °C. This is why ice floats and why ponds freeze top-down, leaving aquatic life alive in the warmer water below.
Worked Examples
Example 10.1: Convert temperatures between scales
(a) Express 37 °C (normal body temperature) in Fahrenheit and Kelvin. (b) Express −40 °C in Fahrenheit (note the surprise!).
\(T = 37 + 273.15 = 310.15\) K.
(b) \(t_F = \tfrac{9}{5}(-40) + 32 = -72 + 32 = -40\) °F. The Celsius and Fahrenheit scales coincide at \(\boxed{-40°}\) — useful trick to remember!
Example 10.2: Steel railway track expansion (NCERT-style)
A steel railway line is 1.0 km long when the temperature is 5 °C. By how much does its length increase if the temperature rises to 50 °C? (\(\alpha_L\) for steel = 1.2 × 10⁻⁵ K⁻¹). What practical engineering arrangement avoids buckling?
\(\Delta L = \alpha_L L \Delta T = (1.2\times 10^{-5}) \times 1000 \times 45 = 0.54\) m = 54 cm.
Engineers leave small expansion gaps between rail sections, or use continuously welded rails clamped tightly so that compressive stress, not buckling, absorbs the expansion.
Example 10.3: Hot iron ring on a wooden wheel (the blacksmith trick)
A blacksmith fits an iron ring of inner diameter 5.231 m onto a wooden wheel of outer diameter 5.243 m. To what temperature must the iron ring be heated so that it just fits over the wheel? Initial temperature = 27 °C; \(\alpha_L\) (iron) = 1.20 × 10⁻⁵ K⁻¹.
\(\Delta T = \dfrac{\Delta L}{\alpha_L L} = \dfrac{0.012}{(1.20\times 10^{-5})(5.231)} = 191\) K.
So the ring must be heated to \(T = 27 + 191 = \boxed{218\,°\text{C}}\). On cooling, the ring contracts and grips the wheel firmly — this is exactly how cartwheels were rimmed traditionally.
Example 10.4: Volume expansion of mercury
A glass flask contains 1000 cm³ of mercury at 20 °C. The temperature rises to 80 °C. Find the apparent change in mercury level if the glass flask itself expands. \(\alpha_V\) (Hg) = 1.82 × 10⁻⁴ K⁻¹; \(\alpha_L\) (glass) = 9 × 10⁻⁶ K⁻¹.
Volume coeff. of glass = \(3\alpha_L = 27\times 10^{-6}\) K⁻¹.
Apparent expansion = \((\alpha_V^{Hg} - \alpha_V^{glass})V\Delta T\)
= \((1.82\times 10^{-4} - 0.27\times 10^{-4})\times 1000 \times 60\)
= \((1.55\times 10^{-4})\times 60000 = 9.30\) cm³.
So mercury appears to rise by 9.30 cm³ — much less than the absolute mercury expansion (10.92 cm³) because the flask also expands.
Interactive 1: Temperature Scale Converter L3 Apply
Type a value in any one box; the others update live.
Interactive 2: Linear Expansion Calculator L3 Apply
Choose material and starting length; vary temperature change.
- Take a long, thin bimetallic strip (or simulate by riveting brass and iron strips together).
- At room temperature note that the strip is straight.
- Hold one end and heat the other end gently with a candle flame.
- Observe the bending and note which metal forms the convex (outer) side.
Application: Bimetallic strips act as thermal switches in electric irons, fire alarms and refrigerator thermostats — when the temperature exceeds a set value, the bend breaks (or makes) the circuit.
Competency-Based Questions
Q1. L1 Remember Define the coefficient of linear expansion of a substance.
Q2. L3 Apply By how much does the cable expand on a 50 °C summer day?
Q3. L3 Apply By how much does it shorten in winter (from 20 °C to −10 °C)?
Q4. L4 Analyse If the cable were not allowed to contract (rigidly fixed at both ends) the resulting tensile stress is \(\sigma = Y\alpha_L\Delta T\). For Y(Al) = 7 × 10¹⁰ Pa, find σ at −10 °C.
Q5. L5 Evaluate Why are pendulums for accurate clocks made of Invar rather than steel?
Assertion-Reason Questions
Assertion (A): A hollow brass sphere expands the same as a solid brass sphere of the same outer radius when heated.
Reason (R): Thermal expansion depends only on the coefficient α and the linear dimensions, not on whether the body is hollow or solid.
Assertion (A): Water at 4 °C is at its maximum density.
Reason (R): Water expands on warming above 4 °C and also expands on cooling below 4 °C.
Assertion (A): The Kelvin and Celsius scales have the same step size.
Reason (R): The Kelvin scale was constructed by shifting the zero of the Celsius scale by 273.15 units, keeping the divisions the same.